Preparation and Characterization of Nano-lignin Biomaterial to Remove Basic Red 2 dye from aqueous solutions

Document Type : Original Research Paper

Authors

Department of Chemistry, University of Payame Noor, P.O.Box 16596-39884, Tehran, Iran

Abstract

The present study prepares alkali lignin (AL) via acidification of black liquor, obtained from a pulp and paper factory. The average molecular weight of AL (equal to 2,530 g/mol) has been determined with gel permeation chromatography. AL has been modified by ethylene glycol, while lignin nanoparticles (LN) has been prepared through acid precipitation technology, their size being assessed by means of DLS to show that the average diameter of the nanoparticles at pH = 4 has been 52.7 nm. Afterwards, it has used AL and LN to remove Basic Red 2 (BR2) from aqueous solutions.
The absorbent structures and morphologies of AL and LN have been investigated using SEM, and FT-IR spectroscopy.
The optimal conditions for the absorption of AL and LN, using 0.1 gr of the absorbent, include 100 min of duration, at pH of 7, and an initial dye concentration amounting to 100 mg/L. Furthermore, the absorption amount has been mathematically described as a function of experimental parameters, modeled by means of Response Surface Methodology (RSM). A central composite design (CCD) has been applied to evaluate the impacts of four independent variables. Optimum absorption values, obtained via empirical methods, completely match with the values, calculated by the program called Design-Expert.
Both absorbent AL and LN show agree with Langmuir Isotherm with maximum absorption capacities of AL and LN being 55.2 mg/gr and 81.9 mg/gr, respectively. The experimental results show that both absorbent LN and AL follow both pseudo-second kinetic and the intraparticle diffusion models.

Keywords


Bahadir, K. and Korbahti, M.A. (2008). Application of response surface analysis to thepHotolytic degradation of Basic Red 2 dye. Chemical Engineering Journal., 138 (2); 166–171.
Batzias, F. A. and Sidiras, D. K. (2007). Simulation of dye ads orption by beech sawdust as affected by pH. J. Hazard. Mater., 141(7); 66-68.
Bulut, E., Özacar, M. and Şengil, İ. A. (2008). Equilibrium and kinetic data and process design for adsorption of Congo Red onto bentonite. J. Hazard. Mater., 154 (28); 613–622.
Camilla, L., Mike, K. and Tanja, B. (2017). Organosolv extraction of softwood combined with lignin-to-liquid-solvolysis as a semi-continuous percolation reactor. Biomass and Bioenergy., 99(8); 147-155.
Camille, F., Marius, R., Alexander, P., Richter, O., Velev, S. and Paunov, N. (2012). Fabrication of Environmentally Biodegradable Lignin Nanoparticles. ChemPHysChem., 13(5); 4235 – 4243.
Caner, N., Kiran, I., Ilhan, S. and Iscen, C. (2009). Isotherm and kinetic studies of Burazol Blue ED dye biosorption by dried anaerobic sludge. Journal of Hazardous Materials., 165(19); 279-284.
Caner, N., Kiran, I., Ilhan, S. and Iscen, C. (2009). Isotherm and kinetic studies of Burazol Blue ED dye biosorption by dried anaerobic sludge. Journal of Hazardous Materials, 165(32); 279-284.
Chowdhury, S., Mishra, R., Kushwaha, P., Saha, P. (2012). Removal of safranin from aqueous solutions by NaOH-treated rice husk: thermodynamics, kinetics and isosteric heat of adsorption. Asia-Pacific Journal of Chemical Engineering. 7( 2); 236-249.
Crini, G. and Badot, P. M. (2008). Application of chitosan, a natural aminopolysaccharide, for dye removal from aqueous solutions by adsorption processes using batch studies. A review of recent literature. Prog. Polym. Sci., 33(8); 399- 447.
Daliang, G., Shubin, W., Gaojin, L. and Huiping, G. (2017). Effect of molecular weight on the pyrolysis characteristics of alkali lignin. Fuel., 193(5); 45-53.
Daliang, G., Shubin, W., Gaojin, L. and Huiping, G. (2017). Effect of molecular weight on the pyrolysis characteristics of alkali lignin. Fuel., 193(29); 45-53.
Fanchiang, J.M. and Tseng, D.H. (2009). Degradation of anthraquinone dye Reactive Blue 19 in aqueous solution by ozonation. ChemospHere., 77(29); 214-221.
Farzaneh, M., Moonis A. K., Ehsan, M. and Bayesti, I. (2015). Soraya Hosseini, Kinetics, thermodynamics, and isotherm studies for the adsorption of BR2 dye onto avocado integument. Desalination and Water Treatment., 53 (5); 826–835.
Frangville, C., Rutkevičius, M., Richter, A.P., Velev, O.D., Stoyanov, S.D. and Paunov, V.N. (2012). Fabrication of environmentally biodegradable lignin nanoparticles. ChempHyschem., 13(18); 4235-43.
Gil, A., Assis, F., Albeniz, S. and Korili, S.A. (2011). Removal of dyes from wastewaters by adsorption on pillared clays. Chemical Engineering Journal.,168(31);1032-1040.
Gomez, V., Larrechi, M.S. and Callao, M.P. (2007). Kinetic and adsorption study of acid dye removal using activated carbon. ChemospHere., 69(7); 1-8.
Gong, R., Li, M., Yang, C., Sun, Y., and Chen, J.  (2005). Removal of cationic dyes from aqueous solution by adsorption on peanut hull. Journal of Hazardous Materials., 121(1); 247-50.
Göran, G. (2015). Softwood kraft lignin: Raw material for the future. Industrial Crops and Products., 77, 23 (17); 845-854.
Guo, X., Zhang, S. and Shan, X. (2008). Adsorption of metal ions on lignin. J. Hazard. Mater.,151 (21); 134–142.
Gupta, A.K., Mohanty, S. and Nayak, S. K. (2014). Synthesis, Characterization and Application of Lignin Nanoparticles (NLPs). Materials Focus., 3(6); 444-454.
Gupta, V. K. Jain, R.  Mittal, A. Saleh, T. A.  Nayak, A.  Agarwal, S. Sikarwar, S. (2012). Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions. Materials Science and Engineering C ., 32(1 ); 12-17.
Gupta, V.K. Agarwal, S.Saleh, T.A. (2011). ynthesis and characterization of alumina-coated carbon nanotubes and their application for lead removal. Journal of Hazardous Materials., 185(1); 17-23.
Gupta, V.K.Srivastava, D.Mohan, S.K. Sharma, S. (1998). Design parameters for fixed bed reactors of activated carbon developed from fertilizer waste for the removal of some heavy metal ions. Waste Management., 17( 8); 517-522.
Ho, Y., Chiu, W. and Wang, C. (2005). Regression analysis for the sorption isotherms of basic dyes on sugarcane dust. Bioresource Technology., 96(20); 1285–1291.
Kaur, S. and Singh, V. (2007). TiO2 mediated pHotocatalytic degradation studies of Reactive Red 198 by UV irradiation. Journal of Hazardous Materials., 141(1); 230-6.
Kayode, O., Adebowale1, B., Olu-Owolabi1, E. and Chigbundu, C. (2014). Removal of Safranin-O from Aqueous Solution by Adsorption onto Kaolinite Clay. Journal of Encapsulation and Adsorption Sciences., 4(3); 89-104.
Madrakian, T., Afkhami, A. and Ahmadi, M. (2012). Adsorption and kinetic studies of seven different organic dyes onto magnetite nanoparticlesloaded tea waste and removal of them from wastewater samples. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy., 99(20); 102-109.
Mahmoud, M., Farah, J. and Farrag, T. (2013). Enhanced removal of Methylene Blue by electrocoag ulation using iron electrodes. Egyptian Journal of Petroleum., 22 (11); 211-216.
Malekbala, M.R., Masoudi, S., Soltani, Kazemi, S. and Hosseini, S. (2012). Equilibrium and Kinetic Studies of Safranine Adsorption on Alkali-Treated Mango Seed Integuments. International Journal of Chemical Engineering and Applications., 3( 16); 160-166.
Malekbala, M.R., Soltani, S. M., Kazemi, S., Hosseini, S. (2012). Equilibrium and Kinetic Studies of Safranine Adsorption on Alkali-Treated Mango Seed Integuments. International Journal of Chemical Engineering and Applications., 3(3; 160-166.
Mall, I. D., Srivastava, V. C., Agarwal, N. K. and Mishra, I. M. (2005). Removal of congo red from aqueous solution by bagas sefly ash and activated carbon: Kinetic study and equilibrium isotherm analyses . ChemospHere., 61(25); 492–501.
Mittal, A. kaKaur, D. Malviya, A. Mittal, J.Gupta, V.K. (2009). Adsorption studies on the removal of coloring agent phenol red from wastewater using waste materials as adsorbents. Journal of Colloid and Interface Science ., 337(2); 345-354.
Mittal, A. Mittal, J. Malviya, A. Gupta, V.K. (2009). Adsorptive removal of hazardous anionic dye “Congo red” from wastewater using waste materials and recovery by desorption. Journal of Colloid and Interface Science., 340(1); 16-26.
Mittal, A. Mittal, J. Malviya, A. kaKaur, D. Gupta, V.K. (2010). Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. Journal of Colloid and Interface Science., 342(2); 518-5277.
Mohan, D., Singh, K. P., Singh, G., Singh, G. and Kumar, K. (2002). Removal of dyes from wastewater using flyash a low –cost adsorbent. Ind. Eng. Chem. Res., 41(2); 3688–3695.
Nigam, P., Armour, G., Banat, I. M., Singh, D. and Marchant, R. (2000). PHysical removal of textile dyes and solid state fermentation of dye-adsorbed agricultural residues. Bioresour. Technol., 72(11); 219-226.
Samaka, I. S. (2014). Removal of Basic Red 2 from Industrial Effluents Using Natural Iraqi Material. Civil and Environmental Research., 6(7);138-148.
Sarocha, P., Guangyan, Q., Ningbo, L., Xiuzhi, S. and Sun, D.W. (2017). Adhesion properties of soy protein adhesives enhanced by biomass lignin. International Journal of Adhesion and Adhesives., 75(7); 66-73.
Shoujuan, W., Yunyun S., Fangong, K., Guihua, Y. and Pedram, F. (2016). Preparation and Characterization of Lignin-Acrylamide Copolymer as a Paper Strength Additive. BioResources., 11(1); 1765-1783.
Shoujuan, W., Yunyun, S., Fangong, K., Guihua, Y. and Pedram, F. (2016). Preparation and Characterization of Lignin-Acrylamide Copolymer as a Paper Strength Additive. BioResources., 11(1); 1765-1783.
Siddique, M., Farooq, R., Khalid, A., Farooq, A., Mahmood, Q. and Farooq, U. (2009). Thermal-pressure-mediated hydrolysis of Reactive Blue 19 dye. Journal of Hazardous Materials.,172(19); 1007-1012.
Sixiao, H. and You-Lo H. (2015). Synthesis of surface bound silver nanoparticles on cellulose fibers using lignin as multi-functional agent. Carbohydrate Polymers., 131(20); 134-141.
Vinod, K., Gupta, A., Mittal, R., Jain, M. M. and Shalini, S. (2006). Adsorption of Safranin-T from wastewater using waste materialsactivated carbon and activated rice husks. Journal of Colloid and Interface Science., 303(3) ; 80–86.
Xiao-Feng, S., Qing, Y., Zhanxin, j. and yajing, l. (2014). Preparation of hemicellulose-g-poly(methacrylic acid)/carbon nanotube composite hydrogel and adsorption properties. Polymer Composites., 35( 1); 45–52.
Yuan, Z., Fei, Y., Junhong, C. and Jie, M. (2016). Batch and column adsorption of methylene blue by grapHene/alginate nanocomposite: Comparison of single-network and double-network hydrogels. Journal of Environmental Chemical Engineering., 4(1); 147–156.
Yuanyuan, G., Qiang, W. and Zhili, L. (2014). Preparation and Evaluation of the Free Radical Scavenging Activities of Nanoscale Lignin Biomaterials. BioResources., 9(4); 6699-6706.
Yufang, T., Yongde, Z., Tao, H., Qiang, Z. and Yongzhen, P. (2016). Preparation of lignin sulfonate-based mesoporous materials for adsorbing malachite green from aqueous solution. Journal of Environmental Chemical Engineering., 4 (16); 2900–2910.
Yuzhong, N., Rongjun, Q., Changmei, S., Chunhua, W., Hou, C., Chunnuan, J., Ying, Z., Xia, S. and Fanling, B. (2013). Adsorption of Pb(II) from aqueous solution by silica-gel supported hyperbranched polyamidoamine dendrimers. Journal of Hazardous Materials., 244(18); 276-286.
Zhu, M.X., Lee, L., Wang, H.H. and Wang, Z. (2007). Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud. Journal of Hazardous Materials., 149(3); 735-41.