Optimisation of Crystal Violet and Methylene Blue Dye Removal from Aqueous Solution onto Water Hyacinth using RSM

Document Type : Original Research Paper

Authors

1 A-704, Bhabha Bhavan, SVNIT, Icchhanath, Surat

2 Civil Engineering Department, Sardar Vallabhbhai National Institute of Technology, Surat, Gujarat 395 007, India.

Abstract

In this study, the adsorptive removal of two dyes (crystal violet (CV) and methylene blue (MB)) with HNO3 pre-treated water hyacinth powder (WHP) adsorbent was analysed. The experiments were designed using response surface methodology (RSM) with variable input parameter pH (2-12), adsorbent dose (0.5-3 g/L), initial dyes concentration (25-200 mg/L) and time (10-180 min). The optimization condition for dye removal were (pH = 7.22, adsorbent dose = 3.0 g/L, initial dye concentration = 195.28 mg/L and time of contact = 99.29 min) for CV with removal of 98.20% and (pH = 9.82, adsorbent dose = 2.96 g/L, initial dye concentration = 199.36 mg/L and contact time = 111.74 min) for MB with removal of 97.843%. The above findings observed that pre-treated water hyacinth powder can be utilised as a cost-effective and efficient adsorbent for dye effluent wastewater treatment. 

Keywords


Ahmad, M.A. and Alrozi, R. (2011). Removal of malachite green dye from aqueous solution using rambutan peel-based activated carbon: Equilibrium, kinetic and thermodynamic studies. Chem. Eng. J. 171, 510–516.
Akar, S.T., Gorgulu, A., Kaynak, Z., Anilan, B. and Akar, T. (2009). Biosorption of Reactive Blue 49 dye under batch and continuous mode using a mixed biosorbent of macro-fungus Agaricus bisporus and Thuja orientalis cones. Chem. Eng. J. 148, 26–34.
Bagheri, A.R., Ghaedi, M., Asfaram, A., Bazrafshan, A.A. and Jannesar, R. (2017).
Comparative study on ultrasonic assisted adsorption of dyes from single system onto Fe3O4 magnetite nanoparticles loaded on activated carbon: Experimental design methodology. Ultrason. Sonochem. 34, 294–304.
Basaleh, A.A., Al-Malack, M.H. and Saleh, T.A. (2019). Methylene Blue removal using polyamide-vermiculite nanocomposites: Kinetics, equilibrium and thermodynamic study. J. Environ. Chem. Eng. 7, 103107.
Bayramoglu, G., Altintas, B. and Arica, M.Y. (2009). Adsorption kinetics and thermodynamic parameters of cationic dyes from aqueous solutions by using a new strong cation-exchange resin. Chem. Eng. J. 152, 339–346.
Bulut, Y. and Aydin, H. (2006). A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination 194, 259–267.
Chiou, M.S. and Li, H.Y. (2003). Adsorption behavior of reactive dye in aqueous solution on chemical cross-linked chitosan beads. Chemosphere 50, 1095–1105.
Chowdhury, S. and Saha, P. (2010). Sea shell powder as a new adsorbent to remove Basic Green 4 (Malachite Green) from aqueous solutions: Equilibrium, kinetic and thermodynamic studies. Chem. Eng. J. 164, 168–177.
Chowdhury, S., Chakraborty, S. and Saha, P. Das (2013). Removal of crystal violet from aqueous solution by adsorption onto eggshells: Equilibrium, kinetics, thermodynamicsand artificial neural network modeling. Waste and Biomass Valorisation 4, 655–664.
Do, T.H., Nguyen, V.T., Dung, N.Q., Chu, M.N., Van Kiet, D., Ngan, T.T.K. and Van Tan, L. (2020). Study on methylene blue adsorption of activated carbon made from Moringa oleifera leaf. In Materials Today: Proceedings, (Elsevier Ltd), pp. 3405–3413.
El-Khaiary, M.I. (2007). Kinetics and mechanism of adsorption of methylene blue from aqueous solution by nitric-acid treated water-hyacinth. J. Hazard. Mater. 147, 28–36.
Fernandes, A.N., Almeida, C.A.P., Menezes, C.T.B., Debacher, N.A. and Sierra, M.M.D. (2007). Removal of methylene blue from aqueous solution by peat. J. Hazard. Mater. 144, 412–419.
Garba, Z.N. and Rahim, A.A. (2014). Process optimisation of K2C2O4-activated carbon from Prosopis africana seed hulls using response surface methodology. J. Anal. Appl. Pyrolysis 107, 306–312.
Garba, Z.N., Bello, I., Galadima, A. and Lawal, A.Y. (2015). Optimisation of adsorption conditions using central composite design for the removal of copper (II) and lead (II) by defatted papaya seed. Karbala Int. J. Mod. Sci. 2, 20–28.
Gosetti, F., Gianotti, V., Angioi, S., Polati, S., Marengo, E. and Gennaro, M.C. (2004). Oxidative degradation of food dye E133 Brilliant Blue FCF: Liquid chromatography-electrospray mass spectrometry identification of the degradation pathway. J. Chromatogr. A 1054, 379–387.
Gupta, V.K. and Suhas (2009). Application of low-cost adsorbents for dye removal - A review. J. Environ. Manage. 90, 2313–2342.
Hou, M.F., Ma, C.X., Zhang, W. De, Tang, X.Y., Fan, Y.N. and Wan, H.F. (2011). Removal of rhodamine B using iron-pillared bentonite. J. Hazard. Mater. 186, 1118–1123.
Huang, L.H., Sun, Y.Y., Yang, T. and Li, L. (2011). Adsorption behavior of Ni (II) on lotus stalks derived active carbon by phosphoric acid activation. Desalination 268, 12–19.
Khaled, A., Nemr, A. El, El-Sikaily, A. and Abdelwahab, O. (2009). Removal of Direct N Blue-106 from artificial textile dye effluent using activated carbon from orange peel: Adsorption isotherm and kinetic studies. J. Hazard. Mater. 165, 100–110.
Khan, T.A., Khan, E.A. and Shahjahan (2015). Removal of basic dyes from aqueous solution by adsorption onto binary iron-manganese oxide coated kaolinite: Non-linear isotherm and kinetics modeling. Appl. Clay Sci. 107, 70–77.
Khosravi, M. and Arabi, S. (2016). Application of response surface methodology (RSM) for the removal of methylene blue dye from water by nano zero-valent iron (NZVI). Water Sci. Technol. 74, 343–352.
Kumar, K., Saravana Devi, S., Krishnamurthi, K., Gampawar, S., Mishra, N., Pandya, G.H., and Chakrabarti, T. (2006). Decolorisation, biodegradation and detoxification of benzidine based azo dye. Bioresour. Technol. 97, 407–413.
Kumari, M. and Gupta, S.K. (2019). Response surface methodological (RSM) approach for optimising the removal of trihalomethanes (THMs) and its precursor’s by surfactant modified magnetic nanoadsorbents (sMNP) - An endeavor to diminish probable cancer risk. Sci. Rep. 9, 18339.
Kushwaha, A.K., Gupta, N. and Chattopadhyaya, M.C. (2014). Removal of cationic methylene blue and malachite green dyes from aqueous solution by waste materials of Daucus carota. J. Saudi Chem. Soc. 18, 200–207.
Lalhruaitluanga, H., Prasad, M.N.V. and Radha, K. (2011). Potential of chemically activated and raw charcoals of Melocanna baccifera for removal of Ni(II) and Zn(II) from aqueous solutions. Desalination 271, 301–308.
Lin, J., Ye, W., Baltaru, M.C., Tang, Y.P., Bernstein, N.J., Gao, P., Balta, S., Vlad, M., Volodin, A., Sotto, A., Luis, P., Zydney, A.L., Van der Bruggen, B., (2016). Tight ultrafiltration membranes for enhanced separation of dyes and Na2SO4 during textile wastewater treatment. J. Memb. Sci. 514, 217–228.
Le Man, H., Behera, S.K. and Park, H.S. (2010). Optimisation of operational parameters for ethanol production from korean food waste leachate. Int. J. Environ. Sci. Technol. 7, 157–164.
Medhat, A., El-Maghrabi, H.H., Abdelghany, A., Abdel Menem, N.M., Raynaud, P.,
Moustafa, Y.M., Elsayed, M.A. and Nada, A.A. (2021). Efficiently activated carbons from corn cob for methylene blue adsorption. Appl. Surf. Sci. Adv. 3, 100037.
Mittal, A., Mittal, J., Malviya, A., Kaur, D. and Gupta, V.K. (2010). Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents. J. Colloid Interface Sci. 342, 518–527.
Mohan, S.V., Ramanaiah, S. V. and Sarma, P.N. (2008). Biosorption of direct azo dye from aqueous phase onto Spirogyra sp. I02: Evaluation of kinetics and mechanistic aspects. Biochem. Eng. J. 38, 61–69.
Myers, R. h., Montgomery, D.C. and Anderson-Cook, C.M. (2009). Response Surface Methodology: Process and Product Optimisation Using Designed Experiments (John Wiley & Sons).
Pathania, D., Sharma, S. and Singh, P. (2017). Removal of methylene blue by adsorption onto activated carbon developed from Ficus carica bast. Arab. J. Chem. 10, S1445–S1451.
Prasad, R. and Yadav, K.D. (2020). Use of response surface methodology and artificial neural network approach for methylene blue removal by adsorption onto water hyacinth. Water Conserv. Manag. 4, 73–79.
Prasad, R., Sharma, D., Yadav, K.D. and Ibrahim, H. (2021). Eichhornia crassipes as biosorbent for industrial wastewater treatment: Equilibrium and kinetic studies. Can. J. Chem. Eng. 1–12.
Rai, A., Mohanty, B. and Bhargava, R. (2016). Supercritical extraction of sunflower oil: A central composite design for extraction variables. Food Chem. 192, 647–659.
Sadhukhan, B., Mondal, N.K. and Chattoraj, S. (2016). Optimisation using central composite design (CCD) and the desirability function for sorption of methylene blue from aqueous solution onto Lemna major. Karbala Int. J. Mod. Sci. 2, 145–155.
Saltabaş, Ö., Teker, M. and Konuk, Z. (2012). Biosorption of cationic dyes from aqueous solution by water hyacinth roots. Glob. Nest J. 14, 24–31.
Samarbaf, S., Tahmasebi Birgani, Y., Yazdani, M. and Babaei, A.A. (2019). A comparative removal of two dyes from aqueous solution using modified oak waste residues: Process optimisation using response surface methodology. J. Ind. Eng. Chem. 73, 67–77.
Sarma, G.K., Sen Gupta, S. and Bhattacharyya, K.G. (2016). Adsorption of Crystal violet on raw and acid-treated montmorillonite, K10, in aqueous suspension. J. Environ. Manage. 171, 1–10.
Tan, I.A.W., Ahmad, A.L. and Hameed, B.H. (2009). Adsorption isotherms, kinetics, thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon. J. Hazard. Mater. 164, 473–482.
Tharaneedhar, V., Senthil Kumar, P., Saravanan, A., Ravikumar, C. and Jaikumar, V. (2017). Prediction and interpretation of adsorption parameters for the sequestration of methylene blue dye from aqueous solution using microwave assisted corncob activated carbon. Sustain. Mater. Technol. 11, 1–11.
Vaez, M., Zarringhalam Moghaddam, A. and Alijani, S. (2012). Optimisation and modeling of photocatalytic degradation of azo dye using a response surface methodology (RSM) based on the central composite design with immobilised Titania nanoparticles. Ind. Eng. Chem. Res. 51, 4199–4207.
Vakili, M., Rafatullah, M., Gholami, Z. and Farraji, H. (2016). Treatment of Reactive Dyes from Water and Wastewater through Chitosan and its Derivatives. In Smart Materials for Waste Water Applications, pp. 347–377.
Wang, S.L., Tzou, Y.M., Lu, Y.H. and Sheng, G. (2007). Removal of 3-chlorophenol from water using rice-straw-based carbon. J. Hazard. Mater. 147, 313–318.
Zhou, W., Zhu, D., Tan, L., Liao, S., Hu, Z. and Hamilton, D. (2007). Extraction and retrieval of potassium from water hyacinth (Eichhornia crassipes). Bioresour. Technol. 98, 226–231.