Characterization of Solid Waste Incineration Fly Ashes and their Heavy Metal Leaching Behavior

Document Type : Original Research Paper

Authors

School of Environment and Architecture, University of Shanghai for Science and Technology, 516 Jun Gong Road, Shanghai 200093, China

10.22059/poll.2022.348489.1624

Abstract

Two fly ashes from municipal solid waste incineration were selected to study their heavy metal leaching behavior. The main purpose of this research is to investigate the characteristics of fly ashes and compare the leaching of heavy metals in different leaching environment. pH and acid neutralization capacity analysis showed that fly ashes were highly alkaline. Fly ashes also contained a variety of heavy metals including Pb, Cu, Cr, Zn, Cd and Ni etc. Leaching studies showed that the alkalinity of fly ashes raised the pH of leaching solution from acidic to basic. Ni, Cu and Zn were strongly bound to ashes and manifested low leaching. In contrast, Cr and Cd had high mobility but their leaching was inhibited by the low solubility of carbonate Cr and Cd. Pb was highly leachable in the alkaline environment with concentration in the leaching solution reached as high as 9.74 mg/L. In addition, the presence of EDTA in the environment also increased leaching. Pb concentration was raised to 16.63 mg/L. This could be attributed to the chelating capacity of EDTA which means that the presence of organics in natural environment should be taken into consideration. 

Keywords


Al-Ghouti, M.A., Khan, M., Nasser, M.S., Al-Saad, K. and Heng, O.E. (2021). Recent advances and applications of municipal solid wastes bottom and fly ashes: Insights into sustainable management and conservation of resources. Environ. Technol. Innov., 21; 101267. 
Atane,s E., Guesta-Garcia, B., Nieto-Marquez, A. and Fernandez-Martinez, F. (2019). A Mixed Separation-immobilization mthod for soluble salts removal and stabilization of heavy metals in municipal solid waste incineration fly ash. J. Environ. Manage., 240; 359-367. 
Cao, Y.N., Luo, J.J. and Sun, S.Q. (2021). Characteristics of MSWI fly ash with acid leaching treatment, J. Fuel Chem. Technol., 49(8); 1208-1218. 
Chaudhary, S. and Banerjee, D.K. (2007). Speciation of some heavy metals in coal fly ash. Chem. Speciat. Bioavailab., 19(3); 95-102.
Chen, W., Chang, F., Shen, Y., Tsai, M. and Ko, C. (2012). Removal of chloride from MSWI fly ash. J. Hazard. Mater., 237-238;116-120. 
Chen, W., Kirkelund, G.M., Jensen, P.E. and Ottosen, L.M. (2017). Comparison of different MSWI fly ash treatment processes on the thermal behavior of As, Cr, Pb and Zn in the ash. Waste Manage., 68; 240-251. 
Fu, B., Liu, G.J., Mian, M.M., Sun, M. and Wu, D. (2019). Characteristics and speciation of heavy metals in fly ash and FGD gypsum from Chinese coal-fired power plants. Fuel, 251; 593-602. 
Guo, B., Liu, B., Yang, J. and Zhang, S.G. (2017). The mechanisms of heavy metal immobilization by cementitious material treatments and thermal treatments: A review, J. Environ. Manage., 193; 410-422.
Jain, S., Banthia, N., Troczynski, T. (2022) Leaching of immobilized cesium from NaOH-activated fly ash-based geopolymers, Cem. Concr. Compos., 133: 104679. 
Jiao, F., Zhang, L., Dong, Z., Namioka, T., Yamada, N. and Ninomiya Y. (2016). Study of the species of heavy metals in MSW incineration fly ash and their leaching behavior. Fuel Process. Technol., 152;108-115.
Liu, Y., Clavier, K.A., Spreadbury, C. and Townsend, T.G. (2019a). Limitation of the TCLP fluid determination for hazardous waste characterization of US municipal waste incineration ash. Waste Manage., 87; 590-596. 
Liu, Z.Y., Yue, Y., Lu, M., Zhang, J., Sun, F.C., Huang, X., Zhou, J.Z. and Qian, G.R. (2019b). Comprehension of heavy metal stability in municipal solid waste incineration fly ash with its compositional variety: A quick prediction case of leaching potential. Waste Manage., 84; 329-339.
Li, M., Xiang, J., Hu, S., Sun, L.S., Su, S., Li, P.S. and Sun, X.X. (2004). Characterization of solid residues from municipal solid waste incinerator. Fuel, 83; 1397-1405.
Loginova, E., Proskurnin, M. and Brouwers H.J.H. (2019). Municipal solid waste incineration (MSWI) fly ash composition analysis: A case study of combined chelatant-based washing treatment efficiency. J. Environ. Manage., 235; 480-488. 
Lu, C.C., Hsu, M.H. and Lin H.P. (2019). Evaluation of heavy metal stability of incinerating recycled aggregate and solidification/stabilization products for construction reuse using TCLP, multi-final pH and EDTA-mediated TCLP leaching tests. J. Hazard. Mater., 368; 336-344. 
Ma, W., Chen, D., Pan, M., Gu, T., Zhong, L., Chen, G., Yan, B and Cheng, Z. (2019) Performance of chemical chelating agent stabilization and cement solidification on heavy metals in MSWI fly ash: A comparative study. J. Environ. Manage., 247; 169-177. 
Race, M., Nabelkova, J., Fabbricino, M., Pirozzi, F. and Raia, P. (2015). Analysis of heavy metal sources for urban creeks in the Czech Republic. Water Air Soil Pollut., 226; 1-10. 
Ramanathan, T. and Ting, Y. (2016). Alkaline bioleaching of municipal solid waste incineration fly ash by autochthonous extremophiles. Chemosphere, 160; 54-61. 
Rassaei, F., Hoodaji, M. and Abtahi, S.A. (2020). Fractionation and mobility of cadmium and zinc in calcareous soils of Fars province. Arab J. Geosci., 13(20); 1-7. 
Shao, Y.Y., Shao, Y.Q., Zhang, W.Y, Zhu, Y., Dou, T., Chu, L.Z. and Liu, Z.D. (2022) Preparation of municipal solid waste incineration fly ash-based ceramsite and its mechanisms of heavy metal immobilization. Waste Manage., 143; 54-60.
Tessier, A., Campbell, P.G. and Bisson, M.J.A.C. (1979). Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem., 51(7); 844-851.
Wang, H.W., Fan, X.X., Wang, Y.N., Li, W.H., Sun, Y.J., Zhan, M.L. and Wu G.Z. (2018). Comparative leaching of six toxic metals from raw and chemically stabilized MSWI fly ash using citric acid. J. Environ. Manage., 208; 15-23. 
Weibel, G., Eggenberger, U., Schlumberger, S., Mä der, U. (2017). Chemical associations and mobilization of heavy metals in fly ash from municipal solid waste incineration. Waste Manage., 62; 147-159. 
Xin, M., Sun, Y., Wu, Y., Li, W., Yin, J., Long, Y., Wang, X., Wang, Y., Huang, Y., Wang H. (2022). Stabilized MSW incineration fly ash co-landfilled with organic waste: Leaching pattern of heavy metals and related influencing factors, Process Saf. Environ. Prot., 165: 445-452.
Xue, Y. and Liu, X. (2021). Detoxification, solidification and recycling of municipal solid waste incineration fly ash: A review. J. Chem. Eng., 420(3); 130349.
Yakubu, Y., Zhou, J., Ping, D., Shu, Z. and Chen Y. (2018). Effects of pH dynamics on solidification/stabilization of municipal solid waste incineration fly ash. J. Environ. Manage., 207; 243-248. 
Ye, N., Chen, Y., Yang, J.K., Liang, S., Hu, Y., Xiao, B., Huang, Q.F., Shi, Y.F., Hu, J.P. and Wu X. (2016). Co-disposal of MSWI fly ash and bayer red mud using a one-part geopolymeric system, J. Hazard. Mater., 318; 70-78. 
Yue, Y., Liu, Z.Y., Liu, Z.Z., Zhang, J., Lu, M., Zhou, J.Z. and Qian G.R.(2019). Rapid evaluation of leaching potential of heavy metals from municipal solid waste incineration fly ash, J. Environ. Manage., 238; 144-152. 
Zhang, Y., Wang, L., Chen, L., Ma, B., Zhang, Y., Ni, W. and Tsang, D.C.W. (2021). Treatment of municipal solid waste incineration fly ash: State-of-the-art technologies and future perspectives, J. Hazard. Mater., 411;125132. 
Zhou, J.Z., Wu, S.M., Pan, Y., Zhang, L.E., Cao, Z.B., Zhang, X.Q., Yonemochi, S,. Hosono, S., Wang, Y., Oh, K. and Qian, G.R. (2015a). Enrichment of heavy metals in fine particles of municipal solid waste incinerator (MSWI) fly ash and associated health risk, Waste Manage., 43; 239-246. 
Zhou, J.Z., Wu, S.M., Pan, Y., Su, Y.W., Yang, L.B., Zhao, J., Lu, Y.S., Xu, Y.F., Oh, K., and Qian, G.R. (2015b). Mercury in municipal solids waste incineration (MSWI) fly ash in China: chemical speciation and risk assessment, Fuel, 158; 619-624.