Synthesis of Activated Carbon from Sugarcane Bagasse and Application for Mercury Adsorption

Document Type: Original Research Paper

Authors

Department of Chemical Engineering, Marvdasht Branch, Islamic Azad University, Marvdasht, Iran

Abstract

With the growth and development of chemical plants, the amount of mercury released in wastewater has increased. Mercury in wastewater contains harmful compounds which are hazardous to the human health and living organisms. Therefore, its removal from wastewater is significant. There are various techniques or methods available for removing mercury from aqueous solutions. This study focused upon the removal of mercury from aqueous solution with commercial activated carbon and activated carbon from sugarcane bagasse.  Activated carbon produced from sugarcane bagasse was used as adsorbent. This adsorbent was used to remove mercury from aqueous solution. For this purpose, first, the optimal mercury solution pH for mercury removal was obtained. Effective parameters such as contact time, initial concentration of mercury, adsorbent dose and agitation speed were investigated. The mercury adsorption was increased when the mass of activated carbon was increased. Increasing the initial mercury concentration leads to decrease in mercury adsorption efficiency. The results of experiments indicated that the speed of the stirrer was not considered to be an effective factor in the mercury adsorption. Experiments were also carried out on a commercial activated carbon. Adsorption results obtained for sugarcane bagasse activated carbon were compared with commercial activated carbon.  The adsorption efficiency was increased as the contact time was increased.  Finally, the experiment was carried out on water samples released from South Pars platforms. In addition to the mercury removal, other heavy metals removal such as lead and cadmium were also carried out.

Keywords


Abu Ismaiel, A., Kheireddine Aroua, M. and Yusoff, R. (2013). Palm shell activated carbon impregnated with task-specific ionic-liquids as a novel adsorbent for the removal of mercury from contaminated water. Chem. Eng. J., 225; 306–314.

Afkhami, F., Karbassi, A. R., Nasrabadi, T. and Vosoogh, A. (2013). Impact of oil excavation activities on soil metallic pollution, case study of an Iran Southern oil field. Environ. Earth Sci., 70; 1219-1224.

Alhamed, Y. A. (2009). Adsorption kinetics and performance of packed bed adsorbed for phenol removal using activated carbon from dates’ stones. J. Hazard. Mater., 170; 763–770.

Alslaibi, A., Abusta, I., Ahmadb, M. A. and Abu Foul, A. (2013). Cadmium removal from aqueous solution using microwaved olive stone activated carbon. J. Environ. Chem. Eng., 1; 589–599.

Anoop Krishnan, K. and Anirudhan, T. S. (2002). Removal of mercury(II) from aqueous solutions and chlor-alkali industry effluent by steam activated and sulphurised activated carbons prepared from bagasse pith: kinetics and equilibrium studies. J. Hazard. Mater., 92; 161–183.

Arias Arias, F. E., Beneduci, A., Chidichimo, F., Furia, E. and Straface, S. (2017). Study of the adsorption of mercury (II) on lignocellulosic material under static and dynamic condition. Chemosphere, 180; 11-23.

Asuquo, E., Martin, A., Nzerem, P., Siperstein, F. and Fan, X. (2017). Adsorption of Cd(II) and Pd(II) ions from aqueous solution using mesoporous activated carbon adsorbent: Equilibrium, kinetics and characterization studies. J. Environ. Chem. Eng., 5; 679-698.

Bouaziz, F., Koubaa, M., Kallel, F., Ellouz Ghorbel, F. and Ellouz Chaabouni, S. (2017). Adsorptive removal of malachite green from aqueous solutions by almond gum: Kinetic study and equilibrium isotherms. Int. J. Biol. Macromol., 105; 56-65.

Dawlet, A., Talip, D., Mi, H. Y. and Ti, M. L. K. Z. (2013). Removal of mercury from aqueous solution using sheep bone charcoal. Procedia. Environ. Sci., 18; 800-808.

Demiral, H. and Gungor, C. (2016). Adsorption of Copper (II) from aqueous solutions on activated carbon prepared from grape bagasse. J. Cleaner Prod., 124; 103-113.

Djilani, C., Zaghdoudib, R., Djazia, F., Bouchekimad, B., Lallame, A., Modarressif, A. and Rogalski, M. (2015). Adsorption of dyes on activated carbon prepared from apricot stones and commercial activated carbon. J. Taiwan Inst. Chem. Eng., 53; 112-121.

Esdaile, L. J. and Chalker, J. M. (2018). The Mercury Problem in Artisanal and Small-Scale Gold Mining. Chem. Eur. J., 24; 6909-6916.

Esfandiari, N., Nasernejad, B. and Ebadi, T. (2014). Removal of Mn(II) from groundwater by sugarcane bagasse and activated carbon (a comparative study): Application of response surface methodology (RSM). J. Ind. Eng. Chem., 20; 3726–3736.

Gonzalez, P. G. and Pliego-Cuervo, Y. B. (2014) Adsorption of Cd(II), Hg(II), and Zn(II) from aqueous solution using mesoporous activated carbon produced from Bambusa vulgaris striata. Chem. Eng. Res. Des., 92; 2715-2724.

Guo, Y., Wang, Z., Zhou, X. and Bai, R. (2017). Removal of mercury (II) from aqueous solution with three commercial raw activated carbons. Res. Chem. Intermed., 43; 2273-2297.

Hadi, P., To, M. H., Hui, C. W., Lin, C. S. K. and Mckay, G. (2015). Aqueous Mercury Adsorption by Activated Carbons, Water Res., 73; 37-55.

Kaghazchi, T. and Shamsijazeyi, H. (2011). Modification of activated carbon using a NOx-containg gaseous by product for enhanced Hg (II) removal from aqueous phase. J. Ind. Eng. Chem., 17; 608-614.

Karbassi, A., Nasrabadi, T., Rezai, M. and Modabberi, S. (2014). Pollution with metals (As, Sb, Hg, Zn) in agricultural solid located close to Zarshuran gold mine, Iran. Environ. Eng. Manage. J., 13; 115-120.

Karbassi, S., Nasrabadi, T. and Shahriari, T. (2016). Metallic pollution of soil in the vicinity of National Iranian Lead and Zinc (NILZ) Company. Appl. Geochem., 75; 1433.

Khoramzadeh, E., Nasernejad, B. and Halladj, R. (2013). Mercury biosorption from aqueous solution by Sugarcane Bagasse. J. Taiwan. Inst. Chem. Eng., 44; 266–269.

Kobya, M., Demirbas, E., Senturk, E. and Ince, M. (2005). Adsorption of heavy metal ions from aqueous solutions by activated carbon prepared from apricot stone. Bioresour. Technol., 96; 1518–1521.

Lu, X., Jiang, J., Sun, K., Wang, J. and Zhang, Y. (2014). Influence of the pore structure and surface chemical properties of activated carbon on the adsorption of mercury from aqueous solutions. Mar. Pollut. Bull., 78; 69-76.

Moktari, Sh. and Faghihian, H. (2015). Modification of activated carbon by 2,6-diaminopyridine for separation of Hg+2 from aqueous solution. J. Environ. Chem. Eng., 3; 1662-1668.

Nasrabadi, T., Ruegner, H., Sirdari, Z. Z., Schwientek, M. and Grathwohl, P. (2016). Using total suspended solids (TSS) and turbidity as proxies for evaluation of metal transport in river water. Appl. Geochem., 68; 1-9.

Nasrabadi, T. and Shirani Bidabadi, N. (2013) Evaluating the spatial distribution of quantitative risk and hazard level of arsenic exposure in groundwater, case study of Qorveh County, Kurdistan Iran. Iranian J. Environ. Health Sci. Eng., 10; 30.

Nayak, A., Bhushan, B., Gupta, V. and Sharma, P. (2017). Chemically activated carbon from lignocellulose wastes for heavy metal wastewater remediation: Effect of activation conditions. J. Colloid Interface Sci., 493; 228-240.

Nazeri, G., Abolghasemi, H. and Esmaieli, M. (2015). Batch adsorption of cephalexin antibiotic from aqueous solution by walnut shell-based activated carbon. J. Taiwan Inst. Chem. Eng., 58; 357–365.

Ogataa, F., Imaia, D. and Kawasakia, N. (2015). Cationic dye removal from aqueous solution by waste biomass produced from calcination treatment of rice bran. J. Environ. Chem. Eng., 3; 1476–1485.

Saad, A., Baka, I., Piquermal, J. Y., Nowak, S., Abderrabba, M. and Chehimi, M. M. (2016) Mesoporous silica/polyacrylamide composite: preparation by UV-graft photopolymerization, characterization and use a Hg (II) adsorbent. Appl. Surf. Sci., 367; 181-189.

Sidiqui, S. H. and Ahmad, R. (2017). Pistachio Shell Carbon (PSC) – an agricultural adsorbent for the removal of Pb (II) from aqueous solution. Groundwater Sustainable Dev., 4; 42-48.

Stuart, B. (2004). Infrared Spectroscopy: fundamentals and applications, Wiley press.

Tan, G., Xu, N., Wang, H. and Sun, W. (2016). Sorption of mercury (II) and atrazine by bio char, modified bio chars and bio char based activated carbon in aqueous solution. Bioresour. Technol., 211; 727-735.  

Wahby, A., Reddam, Z., Mail, R. E., Stitou, M., Silvestre-Albero, J., Sepúlveda Escribano, A. and Rodríguez-Reinoso, F. (2011). Mercury removal from aqueous solution by adsorption on activated carbons prepared from olive stones. Adsorption, 17; 603-609.

Worthing, M. J. H., Kucera, R., Albuquerque, I. S., Gibson, C. T., Sibley, A., Slattery, A. D., Campbell, J. A., Alboaiji, S. F. K., Muller, K. A., Young, J., Adamson, N., Gascooke, J. R., Jampaiah, D., Sabri, Y. M., Bhargava, S. K., Jppolito, S. J., Lewis, D. A., Quinton, J. S., Allis, A. V., Johs A., Bernardo, G. J. L. and Chalker, J. M. (2017). Laying Waste to Mercury: Inexpensive Sorbent Made from Sulfur and Recucled Cooking. Chem. Eur. J., 23; 16219-16230.

Wu, F. C., Tseng, R. L. and  Juang, R. S. (2011). A review and experimental verification of using chitosan and its derivatives as adsorbents for selected heavy metals. J. Environ. Manage., 91; 798-806.

Yang, J., Yu, M. and Chen, W. (2015) . Adsorption of hexavalent chromium from aqueous solution by activated carbon prepared from longan seed: Kinetics, equilibrium and thermodynamics. J. Ind. Eng. Chem., 21; 414-422.

Yao, X., Ma, W. Z., Liu, M., Zhao, X. and Jia, D. (2016). Adsorption of Hg (II) from Aqueous Solution Using Thiourea Functionalized Chelating Fiber. Chinese J. Chem. Eng., 24; 1344-1352.

Yardim, M. F., Budinova, T., Ekinci, E., Petrov, N., Razvigorova, M. and Minkova V. (2003). Removal of mercury (II) from aqueous solution by activated carbon obtained from furfural. Chemosphere, 52; 835–841.

Zabihi, M., Ahmadpourb, A. and Haghighi Asla, A. (2009). Removal of mercury from water by carbonaceous sorbents derived from walnut shell. J. Hazard. Mater., 167; 230–236.

Zhang, S., Zhang, Y., Liu, J., Xu, Q., Xiao, H., Wang, X. and Zhou, H. (2013). Thiol Modified Fe3O4@Sio2 as a Robust, High Effective, and Recycling Magnetic Sorbent for Mercury Removal. Chem. Eng. J., 226; 30-38.

Zhang, F. S., Nriagu, J. and Itoh, H. (2005). Mercury removal from water using activated carbons derived from organic sewage sludge. Water Res., 39; 389-395.

Zho, J., Liu, Y., Zhou, X., Ren, J. and Zhong, C. (2017). Removal of mercury ions from aqueous solution by thiourea-functionalized magnetic biosorbent: Preparation and mechanism study. J. Colloid Interface Sci., 507; 107-118.

Zhu, Y. and Kolar, P. (2014). Adsorptive removal of p-cresol using coconut shell-activated char. J. Environ. Eng., 2; 2050–2058.