Removal of Benzyl butyl phthalate by Polyetheretherketone/polyvinylalcohol nanocomposite Modified with Zinc oxide nanoparticles Adsorbent from Wastewater

Document Type : Original Research Paper

Authors

1 Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran

2 Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

10.22059/poll.2024.371983.2242

Abstract

The applicability of Polyetheretherketone/polyvinylalcohol nanocomposite modified with zinc oxide nanoparticles synthesis for the removal of benzyl butyl phthalate from wastewater. Identical techniques, including BET, FT-IR, XRD, and SEM, have to characterize this unknown material. The investigation shows the applicability of adsorbent PEEK/PVA/ZnONPs, as an available, suitable, and low-cost adsorbent for adequately removing the benzyl butyl phthalate from wastewater. The impacts of variables, including benzyl butyl phthalate concentration, adsorbent, pH, and time (15 mgL-1, 0.3 g, 5.0, and 60 min). Based on the received data, the adsorption of benzyl butyl phthalate on the PEEK/PVA/ZnONPs adsorbent agrees well with the Langmuir adsorption model isotherm (qm = 34.24 mgg-1). The results of the thermodynamic parameter showed a negative enthalpy (-77.0 KJ/mol), a negative Gibbs free energy (-11.7 KJ/mol), and negative entropy (-274.0 J/K.mol). This led to the conclusion that the adsorption process is energetically possible, and exothermic was also spontaneous. This work indicates that the PEEK/PVA/ZnONPs, used as an ecologically adapted, adsorbent holds promise for eliminating benzyl butyl phthalate from wastewater.

Keywords

Main Subjects

Pollution

Articles in Press, Accepted Manuscript
Available Online from 10 April 2024

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